Deodorants (and aerosol cans generally) are gasses, however when the cans they are in are filled up they are under such high pressure that they are forced together into a liquid. As you press the top to spray some of it, it rushes up the tube where there is less pressure, and it becomes a gas again.
This is also why cans get cold when you spray them – as the liquid expands back into a gas it needs energy to do so and sucks heat out of the can and air around it 🙂
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